The anodizing process has three main steps: cleaning and etching, anodizing in an electrolyte bath, and sealing and coloring. In the anodizing tank, metal plates are used as electrodes—one as the anode and one as the cathode. The cathode is the negative electrode, attracting positive ions from the electrolyte solution. During the process, positive aluminum ions leave the aluminum surface, which creates porosity and allows the formation of a durable aluminum oxide layer.
Each step has its own importance.
Cleaning and Etching
Cleaning uses a mild solution to remove machining residues and grease. Sodium hydroxide and nitric acid are common agents to remove surface coatings, so the aluminum surface is free from impurities, necessary for etching. Phosphoric acid can also be used as a pretreatment to clean and prepare the aluminum surface, especially before adhesive bonding or organic coating.
Etching removes surface defects and the natural oxide layer from the aluminum, so it’s ready for anodizing. Temperature and concentration of the sodium hydroxide solution affect the etching process.
Mechanical methods like polishing or bead blasting can also be used to prepare the aluminum surface before anodizing. Chemical polishing is another surface preparation technique to achieve a smooth, glossy finish before anodizing.
Anodizing in Acid Electrolyte Bath
Anodizing involves submerging aluminum in an acid electrolyte bath and applying an electrical current. Sulfuric acid anodize is the most common method for making durable, corrosion resistant aluminum surfaces. The aluminum becomes porous and grows a layer of aluminum oxide as positive and negative ions leave the surface during the process.
The aluminum parts are connected to an electrical circuit and act as the anode. This step is critical for forming the anodic oxide structure that enhances the aluminum atoms properties with a metal electrode.
Sealing and Coloring
Sealing the anodized aluminum closes the pores and protects the surface. Hot DI sealing produces a porous aluminum oxide layer and hydrated aluminum oxide preventing corrosion and improving performance during the sealing process.
Mid temperature sealing uses metal salts in solution like nickel, magnesium or cobalt salts to chemically react with the surface, fill pores and improve sealing quality. This method is good for colored components and reduces surface mineral deposits and defects like sealing smut. The porous surface of anodized aluminum allows for good dye absorption and sealing.
Cold sealing chemistries like nickel-fluoride based formulations operate at room temperature to create a protective fluoro-aluminate layer on the aluminum oxide surface. Nickel fluoride formulations are commonly used in these cold sealing chemistries to improve surface adhesion and meet military and automotive industry standards.
Coloring anodized aluminum involves filling the porous structure with colorants. Pigments are injected into open pores and then sealed to preserve the color of the parts. Metallic salts are used in electrolytic coloring to get bronze or black finish by reacting with the porous surface of the anodized layer, filling pores with colored compounds.